chains were early on, recognised as very dangerous because they have many, many wear points and virtually any failure is catastrophic ( in the technical sense of "causing complete failure" ).
http://www.cmhrc.co.uk/cms/document/1863_66.pdf of the actual chain at Botallack, the only such description I know of.
Flat ropes are good for winding in a single plane, less so for winding round corners so no good for certain types of incline, for example the Middleton Top incline in Derbyshire where the winding house was offset so that wagons could pass the engine house on the same track after ascending the incline
''the stopes soared beyond the range of our caplamps' - David Bick...... How times change .... oh, I don't know, I've still got a lamp like that.