Could someone explain what the problem is with charging Li-ion cells?, I know they are prone to igniting if over charged.
I understand that bog standard chargers depend upon internal battery resistance build up to trigger the trickle charge cycle, does this not happen with Li cells? or is it too small to trigger the charger, or what?
Lithium charging is a very different beast, and relies upon reading the voltage of the cell. It uses a CC/CV curve and will modify it's output over he course of a charge. Internal resistance is more important when looking at the discharge characteristics of the cell.
Have a look here for more detailed information on Li-Ion charging, it has a pretty decent explanation of the stages of charging a cell, and how the CC/CV curve works.
http://batteryuniversity.com/learn/article/charging_lithium_ion_batteries It's not just over charging capacity terms. it's over current on a charge. Your absolute maximum charge rate for most (Li-Ion, LiPo is a different story) cells is 1C, where C is the capacity of the cell. Most recommend charging around .5C For example, if you have a 2500mAH cell, you should really charge around 1250mA, but can push it to 2500mA if you really have to.
If you are charging a pack in parallel, you multiply the cell number by the capacity of the individual cells. Another example, My packs are 3s3p (3 2,500maH cells in series (3s), and 3 of those 3S packs in parallel (3p)). 9 cells, with 11.1v nominal voltage, and a 7500mAH capacity, so normal charge rate is 3750mA, and max is 7500mA.
Edit:- corrected figures, I can't type worth toffee it seems.
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