A summary of ore deposits formed by igneous processesIgneous processes take place in magmatic systems, and involve crystals, immiscible liquids (magma, sulphide melt, oxide melt, water), and gases (as formed when water boils). Chemical and physical processes associated with the separation of crystals or immiscible liquids from magma, give rise to magmatic fractionation, which can produce a range of igneous rock types and may concentrate metals to form ore deposits.
Igneous rocks span a range of compositions — from peridotite to gabbro (basalt) to diorite (andesite) to granite (rhyolite)—the formation of which depend on the source of the magma and the extent to which magmatic fractionation has occurred. Different types of ore deposit are associated with particular types of igneous rocks: magmatic segregation deposits are associated with peridotites and gabbros, pegmatite ore deposits with granites, and porphyry ore deposits with diorites, granodiorites and granites.
Magmatic segregation deposits separate from hot fluid basaltic magmas when either dense early-formed crystals, or dense immiscible liquids (sulphide or oxide), sink towards the floor of a magma chamber and form cumulate layers. Settling of crystals may produce chromite and magnetite ore deposits; settling of sulphide-rich immiscible liquids may produce ore deposits rich in copper, nickel, gold or platinum; settling of oxide-rich immiscible liquids may produce ore deposits rich in iron or iron-titanium oxides. Development of the multiple layering that is typical of many magmatic segregation deposits requires periodic influxes of magma into the magma chamber.
Pegmatites form from granitic magma after anhydrous minerals have crystallized from it, so enriching the remaining melt in water and sometimes incompatible elements, and thus making it particularly fluid. Pegmatites are not often mineralized, but when they are, they can be enriched in valuable metals, including beryllium, caesium, lithium, niobium, rare earth elements (such as cerium), tantalum, thorium, tin, tungsten, uranium and zirconium, many of which rarely form mineral deposits in other circumstances.
Porphyry deposits are formed when metal-rich watery fluids boil and are released explosively from a wet granodioritic magma being emplaced at a high level in the crust. The network of fractures produced, provides pathways for distribution of metal-rich fluids that were derived initially from the magma and subsequently from surrounding rocks. The fractures also provide sites for the deposition of ore minerals, as fluids cool and react with wall rocks. Porphyry deposits provide much of the world's copper and molybdenum, as well as substantial quantities of tin, silver and gold as by-products. They are typically low-grade but extremely large deposits. The Chilean porphyry copper belt and Chuquicamata copper mine - the largest copper producer in the world, being an obvious example.
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