Might I point you in the direction of the last edition of 'Mining History' (Vol. 19 No. 3 Summer 2015) for an article by Simon Timberlake on Mining and Smelting in the Prehistoric period.
There will also be a considerable amount of information in 'The Archaeology of Mining and Quarrying in England: An Archaeological Research Framework for the Extractive Industries in England' which has been produced by a group of us led by Peter Claughton and Phil Newman on behalf of NAMHO, which should be published in the next two or three months.
There was a considerable period from the late Neolithic onwards when copper was smelted and used just as copper. It's usually referred to as the Chalcolithic and fits between the New Stone Age (Neolithic) and the Bronze Age.
For details see: Julian Heath (2012) Life in Copper Age Britain. Amberley Publishing, Stroud.
I quote from Simon's article: The tin question is also an interesting one. Britain emerges into a fully-fledged tin Bronze Age around 2100-1900 BC; a date which is surprisingly early in the evolutionary sequence of development of metal-using technologies, given that use of copper here only begins around 2600-2500 BC. Furthermore, when bronze first appears in these islands, the tin level is high, with between 5-12% tin content being typical of flat axes during the Early Bronze Age (Northover 1999, 223), rising to 10-12% by the Middle Bronze Age. Most likely this reflects the easy availability of alluvial-sourced tin from SW England (W. Devon and Cornwall), and the existence of trade exchange pathways between the tin and copper-producing areas.
At present there is (as far as I am aware - and I have my ear to the ground) no known Bronze Age mining in the Lakes (or in fact in Cornwall or Devon) which is surprising. It may be that the evidence has disappeared but even if the mine itself has gone there are usually the scattered stone hammer tools which are diagnostic of Bronze Age mining. See details of the excavations at Copa Hill, Cwmystwyth, for more information. At Ecton Mine in Staffordshire the presence of these tools was noted as far back as the time of Thomas Bateman, the antiquarian barrow digger of the 1860s.
As in all these matters - there are far more questions than answers.