I confess I have no knowledge of the rules surrounding this - it's not really my bag.
The rules can be relatively simple:
Landowner permission required for take-off and landing.
Don't fly closer than 50m to people and property "not under your control".
Max height 120m.
Max distance 500m away from the operator.
Maintain visual line of sight.
Daylight only.
Appropriate weather.
Observe any flight restrictions that apply to the area (airports, power stations, etc.)
CAA permission required for all commercial work.
Apart from those, it's all about showing that you can complete the flight without risking injury or damage to people or property. So a written site assessment with a diagram (eg. Google Earth) showing footpaths or anything of concern is a good idea. Include relevant phone numbers (hospital, police, CAA, nearest air traffic control) to call if it heads off over the horizon.
And be competent to fly in that location.
"The true crimefighter always carries everything he needs in his utility belt, Robin"