Getting hold of a copy of Caves of the Peak District is probably your best bet (check the DCA website for stockists, or buy online from Mike Moore), it's not absolutely comprehensive but it's a good general guide.
For non-SRT explores, try Mouldridge Mine, Devonshire Cavern, Masson Cavern or Wapping Mine/Cumberland Cavern. There are also several smaller mines down the Via Gellia but some of them take a bit of finding!
Follow the horses, Johnny my laddie, follow the horses canny lad-oh!