Interesting topic and one which would be empirically easy to determine.
How does LEL and HEL vary with air pressure?
You could also say:-
How does LEL and HEL vary with air concentration?
As O2 concentration is reduced, LEL goes up and HEL comes down, until there is no longer an explosive limit, because combustion isn't supported.
So, then you would go onto how methane leaches out of the rocks and this would be hugely variable with the type of surrounding rock, the type of coal, the overburden and probably the +/- 5% of air pressure from average wouldn't do very much to alter the methane limits within the usual and quite mine-specific amounts.
It would suggest from basic chemistry that high atmospheric pressure would increase the effective concentration of O2, which would make the lower explosive limit as low as possible. However, the lowest atmospheric pressure would give the greatest dP for degassing of the rocks.
What you probably want is a huge low, followed by a mega high perhaps supported by chaps working air tools to create the most explosive environment.
Rather than looking at historical data, I would look at methane readings (from a modern gas meter) in Coal Mines and see how the data stacks up.