@ geraldus: Bwa Maen means stone bow or stone arch and describes the very prominentl anticline exposed at the popular car park below the mines. Its name has been used for both a cave and for one of the mines.
@ Peter: Three useful books:
K.Jones "The Caves and Mines of the Sychryd Gorge" (Part 9 of Limestones and Caves of Wales),various editions published by Tony Oldham at various locations, from the 1990s onwards.
T.Oldham "The Silica Mines of the Little Neath Valley"),various editions published by Tony Oldham at various locations, from the 1990s onwards.
"Memoirs of the Geological Survey: Special Reports on the Mineral Resources of Great Britain: vol.6: Refractory Materials: ganister and silica-rock - sand for open-hearth steel furnaces - dolomite: resources and geology", 2nd ed, London, 1920. The gazetteer portion of this volume lists, amongst others "Bwamaen and Kilhepste Quarries", giving locations for them as Lat.51 deg, 45 min, 32 sec, Long.3 deg, 34 min, 15 sec, and Lat.51 deg, 45 min, 32 deg, Long. 3 deg, 34 min, 10 min. Hopefully this will enable you locate these two workings, Peter. Also in the Glynneath area it lists Ton-y-gilfach Quarry (Lat.51 deg, 45 min, 55 sec, Long.3 deg, 35 min, 50 sec), Lluest Quarry (Lat.51 deg, 45 min, 55 sec, Long.3 deg, 35 min, 40 sec), Toryfoel Quarry (Lat 51 deg, 46 min, 10 sec, Long.3 deg, 32 min, 25 sec) and Toryfoel Sandpit (Lat.51 deg, 46 min, 4 sec, Long.3 deg, 32 min, 20 sec).
D.M.Rees published a photo of the 1960s underground workings in "Historic Industrial Scenes: Wales", Ashbourne: Moorland Publishing, 1978, and another in "The Industrial Archaeology of Wales", Newton Abbot: David & Charles, 1975 and added a short description of the mine in the latter volume, terming the well-known and extensive workings much-explored by cavers and mining enthusiasts, as "Dinas Mine".
There is some useful information on the silica industry in D.R.Phillips "The History of the Vale of Neath", Swansea, 1925, facsimile pub. Swansea: West Glamorgan Archive Service & Neath Borough Council, 1994. There are a few scant mentions of the mines in E.Jenkins (ed.) "Neath and District: a symposium", Neath, 1974.
The mines have featured in a numbe rof caving clubs' publications but I'm sure that you've already quarried (Ho! Ho!) that source.