Bit of a side issue, but there have been two Carbon Monoxide issues that I'm aware of in lead mines - one was at Long Rake Mine near Bradwell in 2009 I think, where two visitors came out feeling very ill and testing showed high levels in their blood. It was never demonstrably proven that the gas was actually in the mine though, and the place is still closed at the landowner's request as a result. I've still never been :(
The other was at a mine shaft on private farmland near Elton a few years ago that had swallowed a cow, and an initial test with a lowered Altair showed very high levels of CO. A return visit was made a week later with a shaft-inspection robot with a gas monitor - I was actually present at that one - and the readings this time were even higher - deadly in fact, so we were unable to even descend a little way. Both monitors were well within calibration and worked fine, so we still have no idea what was causing the Carbon Monoxide. On a limestone plateau on farmland I can't think of anything - there is lava down there, but not much else unusual that's 'natural'. The farmer said he'd lit some newspaper and dropped it on his first visit. My instinct is that whatever it was causing the huge amount, it was below the cow, which was jammed about 30m down at the time, and that whatever it was, it probably shouldn't have been down there.