I have no special knowledge or focused interest in Wrysgan Quarry. I hold no information on this quarry.
In the absence of any other reply to your enquiry, I searched the TNA online catalogue and the LG online search facility to provide you with information.
The LoM and LoQ were suggested as being very likely to answer your query because, from past experience of using these publications, I have found them to be ideal for answering the sort of query which you have posed. Other sources that might answer your query would be reports in local newspapers, and the archives of the mineral landlords (if they survive and are in a public repository). The LoM and LoQ usually offer a faster (and often a more accurate) indication of whether any specific mine or quarry was operating and to what degree (output is usually proportional to workforce size).
This, I'm afraid, exhausts the information that I can find and the suggestions that I can make in respect of this query.
I wish you every success with your ongoing research.